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Advanced Thermodynamics

Advanced Thermodynamics. Instructor: Prof. Nanda Kishore, Department of Chemical Engineering, IIT Guwahati. In any chemical process, often one encounters interaction between phases where transfer of species takes place from one phase to another. There exist several situations of vapor-liquid, liquid-liquid, vapor-liquid-liquid, solid-liquid equilibria in chemical engineering processes. Often these situations are dealt with assumption of ideal behavior and binary systems but in reality non-ideality and multicomponent mixtures exist and accordingly one has to deal with such situations. This course offers step-by-step understanding of required thermodynamic properties to handle such equilibrium cases and explore possible ways of solving problems associated with non-ideality in VLE, LLE, VLLE and SLE for multicomponent mixtures. (from nptel.ac.in)

Lecture 09 - Molecular Theory of Corresponding States


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Introduction of Phase Equilibria
Lecture 01 - Introduction of Phase Equilibrium
Lecture 02 - Classical Thermodynamics of Phase Equilibria
Lecture 03 - Classical Thermodynamics of Phase Equilibria (cont.)
Estimation of Thermodynamic Properties
Lecture 04 - Thermodynamic Properties from Volumetric Data
Lecture 05 - Fugacity from Volumetric Data
Lecture 06 - Fugacity from Volumetric Data (cont.)
Potential Energy Functions and Intermolecular Forces
Lecture 07 - Intermolecular Forces and Non-ideal Behaviour
Lecture 08 - Intermolecular Forces - Potential Energy Functions
Molecular Theory of Corresponding States
Lecture 09 - Molecular Theory of Corresponding States
Lecture 10 - Molecular Theory of Corresponding States (cont.)
Intermolecular Interactions and EoS
Lecture 11 - Intermolecular Potential and EoS
Lecture 12 - Virial Coefficients from Potential Functions
Lecture 13 - Virial Coefficients from Corresponding States Theory
Gaseous Mixtures and Fugacity
Lecture 14 - Fugacities in Gaseous Mixtures
Lecture 15 - Fugacities in Gaseous Mixtures (cont.)
Lecture 16 - Fugacities in Gaseous Mixtures (cont.)
Liquid Mixtures and Fugacity
Lecture 17 - Liquid Mixtures and Excess Functions
Lecture 18 - Excess Functions and Activity Coefficients
Lecture 19 - Activity Coefficients and Thermodynamic Consistency
Models for Activity Coefficients using Excess Gibbs Energy
Lecture 20 - Models for Excess Gibbs Energy
Lecture 21 - Models for Excess Gibbs Energy (cont.)
Lecture 22 - Models for Excess Gibbs Energy (cont.)
Vapour-Liquid Equilibria of Multicomponent Non-ideal Systems
Lecture 23 - Vapour-Liquid Equilibrium
Lecture 24 - Vapour-Liquid Equilibrium (cont.)
Lecture 25 - Vapour-Liquid Equilibrium (cont.)