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Chemistry 202: Organic Reaction Mechanisms II

Chemistry 202: Organic Reaction Mechanisms II (Winter 2014, UC Irvine). Instructor: Professor David Van Vranken. Topics include the shape of frontier molecular orbitals, nucleophilic sigma bonds, the organic chemistry of phosphorus and sulfur, pericyclic reactions, ene reactions, electrocyclic reactions, sigmatropic reactions, kinetics, rate equations, selectivity and reaction coordinate-energy diagrams, transition state theory, and radical reactions.

Lecture 15 - Sigmatropic Reactions (cont.)


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Lecture 01 - Introduction
Lecture 02 - A Review of Orbitals
Lecture 03 - The Shape of Frontier Molecular Orbitals
Lecture 04 - Nucleophilic Sigma Bonds
Lecture 05 - Nucleophilic Sigma Bonds (cont.)
Lecture 06 - The Organic Chemistry of Phosphorus
Lecture 07 - Phosphorus Chemistry (cont.), The Organic Chemistry of Sulfur
Lecture 08 - The Organic Chemistry of Sulfur (cont.), Pericyclic Reactions
Lecture 09 - Pericyclic Reactions: The Diels-Alder Reaction
Lecture 10 - Pericyclic Reactions: The Diels-Alder Reaction (cont.)
Lecture 11 - Beyond [4+2] Cycloadditions
Lecture 12 - Retrocycloadditions, Ene Reactions
Lecture 13 - Electrocyclic Reactions
Lecture 14 - Electrocyclic Reactions (cont.), Sigmatropic Reactions
Lecture 15 - Sigmatropic Reactions (cont.)
Lecture 16 - Kinetics and Rate Equations
Lecture 17 - Rate Equations (cont.), Selectivity and Reaction Coordinate-Energy Diagrams
Lecture 18 - Selectivity and Reaction Coordinate-Energy Diagrams
Lecture 19 - Selectivity (cont.), Transition State Theory
Lecture 20 - Transition State Theory, Temperature, and Half-Lives
Lecture 21 - Mechanistic Tools
Lecture 22 - Radical Structure and Reactivity
Lecture 23 - Radical Reactions