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Chemistry 51A: Organic Chemistry

Chemistry 51A: Organic Chemistry (Fall 2014, UC Irvine). Instructor: Professor Susan King. Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds.

Lecture 24 - Factors that Affect the Rate of the SN1 Reaction

Time Lecture Chapters
[00:01:14] 1. Stereochemistry of the SN1 Reaction
[00:03:16] 2. Factors that Affect the Rate of the SN1 Reaction
[00:07:46] 3. The Structure of the Substrate
[00:15:25] 4. Hyperconjugation
[00:21:42] 5. The Structure of the Transition State: Hammond's Postulate
[00:32:24] 6. The Effect of Solvent on the Rate of Reaction
[00:37:29] 7. Benzylic Halides, Allylic Halides, Methoxymethyl Halides, Vinylic Halides, and Aryl Halides
[00:44:09] 8. Vinylic and Aryl Halides do not undergo SN1 or SN2 Reactions

Go to the Course Home or watch other lectures:

Lecture 02 - Ionic Bonding & Covalent Bonding
Lecture 03 - Resonance Structures
Lecture 04 - Molecular Orbital Theory & Hybridization
Lecture 05 - Bonding in Small Molecules & Reactive Intermediates
Lecture 06 - Bonding in Molecules
Lecture 07 - Electronegativity & Polarity of Molecules
Lecture 08 - Intro to Acids and Bases
Lecture 09 - Structural Effects of pKa
Lecture 10 - Introduction to Organic Molecules and Functional Groups
Lecture 11 - Intermolecular Forces
Lecture 12 - Conformations of Acyclic Alkanes
Lecture 13 - Systematic Nomenclature
Lecture 14 - Conformations of Cycloalkanes
Lecture 15 - Disubstituted Cycloalkanes and Oxidation of Alkanes
Lecture 16 - Stereochemistry
Lecture 17 - Properties of Enantiomers and Stereoisomers
Lecture 18 - Enantiomeric Resolution
Lecture 19 - Understanding Organic Reactions
Lecture 20 - Equilibrium and Kinetics
Lecture 21 - Alkyl Halides and Nucleophilic Substitution
Lecture 22 - Nucleophilic and Bimolecular Substitution
Lecture 23 - Substitution, Nucleophilic, Unimolecular - SN1 Reactions
Lecture 24 - Factors that Affect the Rate of the SN1 Reaction
Lecture 25 - Nuclear Magnetic Resonance Spectroscopy
Lecture 26 - Proton Nuclear Magnetic Resonance (HNMR)
Lecture 27 - Spin-Spin Coupling
Lecture 28 - Carbon-13 Nuclear Magnetic Resonance (CNMR)